You cannot really make all the time units a multiple of 10 to each other as a day, months and a year, for example, are defined by external factors.
You could perhaps change seconds so a day would be exactly 100k seconds, which would make seconds slightly shorter than they now are but that wouldn't really change the fact that a year is 365.25 days and that a month is either 27.32 or 29.53 days depending on how you measure it.
A day is the spin of the Earth and a Year is the orbit of the Earth, but months are completely arbitrary because we (Western world) don't use Lunar cycles for months.