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I haven't had any problems running my Steam library under Linux Mint. Older games, like Deus Ex and Giants: Citizen Kabuto I can run directly in Wine.
If I could get Vortex Mod Manager working properly under Linux, I wouldn't need Windows at all.
Nexus is running Linux tests for their new mod manager RIGHT NOW. I believe its still limited to Stardew Valley for now while in alpha, but they're making strides here! https://nexus-mods.github.io/NexusMods.App/users/GettingStarted/
You can!
Add Steamtinkerlaunch to your steam proton list with protonup‐qt Then, select it under the force compatibility menu. From there, just click the run vortex mod manager button.
You can also run steamtinkerlaunch standalone, which is what I did for cyberpunk2077, but I feel like I did more manual file moving than I had to.
Edit: can't spell today